Yes, but only the normal points.
The procedure can be made from "Service of Payment with Rakuten Points" on Rakuten e-NAVI.
Also, the amount of the points receivable after the purchase is the same!
To use the service, make sure that the bank account registration is done and the payment of the previous charged bills are fully made.
For more details / cautions of "Service of Payment with Rakuten Points", click the link below.
No cancel or change is accepted. Check the detail carefully when proceeding.